A System to capture the exhaust gases from vehicles mainly co2 where gases from muffler enter into the catalytic converter where gases like CO(carbon Monoxide), HCs(Hydrocarbons) and NOx (Nitrogen Oxide) gets converted into CO2, H2O and NO2 respectively. These gaseous mixture are then transferred to two small cylinder arrangements for separating the CO2 from other flue gases via hydrate separation method. At the end of day this stored CO2 is dumped into the artificial green house installed at petrol pump in which natural conversion of CO2 to O2 takes place. Keywords: Capture collect, Exhaust gases, Vehicles, Catalytic converter, Cylinder, Hydrate separation..